The middleweight title fight is one of five title bouts on the card for the evening, and tickets for the event can be purchased at the Encana Events Centre Box Office, or the Fivestar Training Facility. Stewart will be entering the bout with a record of 5-2, and will be squaring off against Matt “The Riotmaker” Baker for the Fivestar Fight League’s middleweight title. It won’t be the first time these two have met, as Stewart previously dropped a split decision to Baker in 2010.Stewart says that this time around he’ll be better prepared for Baker.“I’ve been working on my cardio. My first fight, I didn’t have as much time to train as this fight,” he says. “I wasn’t in good enough shape for it, so I got gassed right away so I think that will make the difference. My striking is a lot better, and I have another two years of training in.”- Advertisement -Baker meanwhile enters the contest with a record of 8-3 and was victorious in his last fight in July of last year.Stewart says that Baker is a fighter who likes to take things to the ground.“He does a lot of jiu-jitsu, from what I’ve seen, a lot of ground and pound. He does a lot of take downs as well.”Advertisement
Statistical highlights on the fourth day of the second cricket Testbetween India and New Zealand on Monday .# India (262/5) haverecorded their third highest fourth innings successful chase in India,behind the 387 for four against England in Chennai in 2008-09 and 276for five against West Indies in Delhi in 2011-12.# India’s above score is their fifth highest fourth inningssuccessful chase in Test Cricket — the highest is 406 for four againstthe West Indies at Port of Spain in 1975-76.# India enjoy 100%winning record against New Zealand at Bangalore, winning all three — by 172 runs in 1988-89; by 8 wickets in 1995-96 and by 5 wickets in 2012.# India’s 2-0 series win is their third in a row against New Zealand — their previous two series wins being 1-0 in 2008-09 in New Zealandand 1-0 in 2010-11 in India.# Only once before India had wonthree successive series against against New Zealand — 2-0 in 1955-56 in India, 1-0 in 1964-65 in India and 3-1 in 1967-68 in New Zealand.# India have won three Tests in succession against New Zealand — by an innings and 198 runs at Nagpur in 2010-11 followed by an innings and 115 runs at Hyderabad and by 5 wickets at Bangalore.# India had first won three Tests in a row for the first time against New Zealandin the 1960s — by 8 wickets at Wellington, by 272 runs at Auckland in1967-68 and by 60 runs at Mumbai in 1968-69.# Mahendra Singh Dhoni has played four successive innings of 45 ormore against New Zealand — 98 at Nagpur in 2010-11; 73 at Hyderabad and 62 & 48 not out at Bangalore in the just concluded series.# Dhoni is averaging 60-plus against New Zealand — 482 runs in 10 innings, including five fifties, at an average of 60.25. # In Indian wins, Dhoni is averaging 49.57 — 1636 runs in 40 innings, including three centuries and 12 fifties.# Dhoni’s impressive winning % of 48.71 is the best amongst the Indiancaptain (minimum five Tests) — 19 wins, 10 defeats and 10 drawn gamesout of 39 played.# The five-wicket win at Bangalore is India’s 14th out of 20 playedat home under Dhoni’s leadership — the most by an Indian captain onIndian soil, overtaking Mohammad Azharuddin’s tally of 13 wins in 20Tests.# The unbroken match-winning 96-run sixth wicket partnership between Dhoni and Kohli is India’s third highest in the fourth innings of aTest match — the highest is 136 between Sachin Tendulkar and NayanMongia against Pakistan at Chennai in January 1999.# Sachin Tendulkar has totalled 1590 runs at an average of 37.85 in57 innings — a record for most runs in the fourth innings in Tests,bettering Rahul Dravid’s tally of 1575 (ave.40.38) in 57 innings.# Tendulkar has been dismissed ‘bowled’ in three innings in a row — a dubious distinction recorded by him for the second time in Tests –the first instance was against England in England in 2002 when he wasbowled by Matthew Hoggard, Dominic Cork and Michael Vaughan.# Only Rahul Dravid (55) and Allan Border (53) are ahead of Tendulkar’s tally of 51 ‘bowled’ dismissals.# Suresh Raina has recorded his sixth duck in Tests — his second against New Zealand.# Virat Kohli has posted five innings of fifty or more in succession inTests in India — 52 & 63 against the West Indies in Mumbai in2011-12 followed by 58 at Hyderabad, 103 & 51 not out at Bangalore– all three in the series against New Zealand.# Kohli enjoys an outstanding record in Tests in India — his tallybeing 327 at an average of 81.75. He became the sixth Indian player topost a hundred and a fifty in a Test match against New Zealand. RahulDravid had registered the said feat twice, including a century in eachinnings once.# Kohli has got his first Man of the Match award for posting twoexcellent knocks. He has registered a hundred and a fifty in the sameTest match for the first time.# His aggregate of 154 (103 &51 not out) is his best in a Test match, bettering the 138 (116 &22) against Australia at Adelaide in January this year.# Kohli’s run aggregate of 212 (ave. 106.00) is bettered only by Cheteshwar Pujara’s 216 in the present series.# Zaheer Khan has become the eighth Indian bowler to complete 100 wickets or more in India.# Pujara has top-scored in the series — 216 at an average of 72.00in three innings, including a hundred — his best performance in a Testseries.# Ravichandran Ashwin has been adjudged the Player of the Series for capturing 18 wickets at 13.11 runs apiece — the most by abowler in the series.# Besides his excellent bowling performance, he has totalled 69 runs at an average of 69.00 as a batsman.# Ashwin’s Player of the Series award is his second in Tests — the first was for his superb tally of 22 wickets at 22.90 runs apiece and making121 (ave. 40.33) against the West Indies in India in 2011-12.# Ashwin, in four Indian victories, is averaging 17.74, claiming 31wickets, including four instances of five wickets or more and oneinstance of ten wickets in a Test match.# Sehwag and Gambhir were associated in a stand of 77 — India’s first fifty-plus partnership in 12 innings in Tests.# Sehwag, with one six today, took his sixes’ tally to 89, bettering Brian Lara’s tally of 88. Only Adam Gilchrist (100) and Jacques Kallis(92) have posted more sixes than Sehwag in Tests.advertisementadvertisement
WILMINGTON, MA — Wilmington Pop Warner is holding a Registration Night for interested football players (Grades 2-6 for next school year) and cheerleaders (Grades 2-8 for next school year) on Tuesday, April 2, 2019, from 6pm to 8pm, in the Town Hall Auditorium.All new players must have original birth certificate with seal.Fore more information and registration details, click HERE.Like Wilmington Apple on Facebook. Follow Wilmington Apple on Twitter. Follow Wilmington Apple on Instagram. Subscribe to Wilmington Apple’s daily email newsletter HERE. Got a comment, question, photo, press release, or news tip? Email firstname.lastname@example.org.Share this:TwitterFacebookLike this:Like Loading… RelatedWilmington Pop Warner To Hold Registration Night On April 3In “Sports”Wilmington Pop Warner To Hold Registration Night On April 24; Online Registration Now OpenIn “Sports”Wilmington Pop Warner’s Foresyth, Penney, Roberts, Smolinsky, Williams & Zaccagini Named ‘All-American Scholars’In “Sports”
The country’s youth have several reasons to cheer about the Budget, with Finance Minister Arun Jaitley sticking to Narendra Modi’s ambition of galvanising the large demographic group to push development of the country. India is said to have one of the largest youth population in the world, with two-thirds Indians below the age of 35 years.The Union Budget holds several schemes and promises that look set to bring the country’s youth to take charge in the future.From offering them skills training and giving them incentives to start businesses, to setting up sports facilities and premier educational institutes, the government’s Budget looks to capitalise on this age group.Skill India Programme: This national multi-skill programme announced by the government on Thursday is meant to train the youth in several professional skills. With an emphasis on employability and entrepreneurial skills, the government has set aside ₹100 crores for this programme. It will also provide training and support for traditional professions like that of welders, carpenters, cobblers, masons, blacksmiths, and weavers.Young Leaders Programme: “The youth of India are pragmatic, forward-looking and wish to be leaders in all fields. In order to promote leadership skills, I propose to set up Young Leaders Programme with an initial allocation of ₹100 crore,” the finance minister announced on Thursday. Jaitley allotted another ₹100 crore to promote village youth to take up entrepreneurship.Facilitating jobs: Jaitley said the government would work towards converting employment exchanges set up under the Employment Exchanges (Compulsory Notification of Vacancies) Act, 1959 that primarily offer information on availability of jobs into career centres, where the youth will also be offered counselling on selecting jobs based on their aptitude and skills.₹10,000 crore assistance for start-ups – In order to help entrepreneurial youth in the country to start up their own businesses, the government has set aside a ₹10,000 crore fund to provide venture capital for the micro, small and medium enterprises. It also announced ₹200 crore for establishing a technology centre network to promote innovation and entrepreneurship.Five more IITs, IIMs: The Modi government has decided to take the number of IITs and IIMs, the most premier institutions in the country, up to 21 and 18 respectively. The government also announced that four medical instutions on the lines of AIIMS (All India Institute of Medical Sciences) will be set up in the country.National-level Sports Academies: The current state of sports in the country is much below the international standard, and the focus of the government was to ensure the youth of the country get good sports facilities. The government has assured that academies with international-level facilities for training of accomplished athletes and for nurturing talent at junior and sub-junior level will be set up for shooting, archery, boxing, wrestling, weightlifting and various track and field events. Jaitley also announced ₹200 crore for upgrading the indoor and outdoor sports stadiums in Jammu and in Kashmir Valley to international standards.Sports University: The government has allotted ₹100 crore to set up a national sports university at Manipal.Amendment to Apprenticeship Act: Jaitley promised that the Apprenticeship Act will be suitably amended to meet the current needs of the industry as well as the youth. “Comparing the size of the Indian economy, the performance of the Apprenticeship Training Scheme is not satisfactory and a large number of training facilities in the industry are unutilised,” he said during his speech.
mirza fakhrul islam alamgirBangladesh Nationalist Party (BNP) on Monday opposed the decision of Bangladesh and Myanmar to form a joint working group to start the repatriation process of all the Rohingyas staying in Bangladesh, saying it is an uncertain process to resolve the crisis, reports UNB.”The formation of a joint working group is an uncertain process to resolve the issue. Such a decision has manifested that the government is going to fail to have a quick solution to the Rohingya crisis. It’s also failed to make the international community understand the dangerous situation Bangladesh is now facing,” said BNP secretary general Mirza Fakhrul Islam Alamgir.Speaking at a documentary screening programme, the BNP leader renewed their party’s call for forging a national unity to overcome the Rohingya crisis.”We’ve long been talking about forming a national unity to face the challenge. Unfortunately, the government is not paying any heed to it as its policy is to divide the nation.”He urged the government to call a national convention to forge the unity and take steps to send an all-party delegation to different countries to push for resolving the problem.Jatiyatabadi Samajik Sangskritik Sangstha (Jasas) screened the documentary at Kendrio Kochi Kachar Mela auditorium on the plight of Rohingyas and repression on them.Earlier at a meeting of officials of the Bangladesh and Myanmar at the state guesthouse Padma, the two countries agreed to form a joint working group to start the repatriation process of all the Rohingyas living in Bangladesh, which Dhaka sees as a “progress.””It’ll soon be formed and I’m hopeful (about a solution),” Foreign Minister AH Mahmood Ali told reporters in the afternoon mentioning that Myanmar came up with the proposal of repatriation of the Rohingyas.He, however, said the composition of the joint working group will be finalised later. “We’ll give our names from our side while they’ll give their names [for the joint working group].”Fakhrul said the government has failed to portrait the Rohingya crisis and genocide against them by the Myanmar authorities before the international community.”People of Bangladesh have come under an attack through the problem. The government has failed to convince the international community how humanity, and Bangladesh’s independence, sovereignty, economy, environment and society have been affected by the Rohingya crisis.”He also criticised the government for not sending any high-profile delegation to any country and for not intensifying its diplomatic efforts to get influential countries’ support to resolve the Rohingya crisis.He also urged the country’s people to get united to drum up a strong public opinion across the country and abroad to stop persecution on Rohingyas and force the Myanmar authorities to take back their citizens ensuring their rights, citizenship and dignity.
Listen Al OrtizImmigration lawyer Silvia Mintz (right) gave a lecture to cadets from the Houston Police Department when they visited the Denver Harbor Multi-Service Center, which is located in a part of Houston where many residents are immigrants from Latin American countries, as part of HPD’s diversity tour initiative.The quality of the training of police officers in Texas has been in the spotlight recently and incidents such as the arrest of Sandra Bland in Waller County last year and the shooting of Alva Braziel in Houston this past summer have raised questions about how law enforcement deals with diversity and de-escalation tactics.One of the measures the Houston Police Department has taken recently is a tour of the city to teach cadets about its diversity.The tour makes stops in African-American, Asian, Latino and Muslim neighborhoods.“We recruit nationwide and, so, many cadets don’t really understand the history of Houston and, so, we’ll take them out to Acres Homes, we’ll take them out to Meyerland, we’ll take them out to the Fifth Ward and community members will engage them and speak with them and then they’ll take the bus tour and kind of get a cultural history of Houston,” explains Assistant Chief Charlie Vazquez, who oversees the Professional Development Command at HPD.Vazquez says learning about Houston’s diversity is useful for the cadets because they are introduced to members of the community who can help them establish trust in the groups they will be working with and that is a trust that eventually should lead to more effective policing.Cadet Egla Flores says the tour allows trainees to learn small details that will help them when they interact with the public.She gives an example of something she learned at the Islamic Society of Greater Houston when she took the tour.“If we try to shake the woman’s hand they probably wouldn’t shake our hand, they would place their hands over their chest. It’s just little things that we learn from different communities,” Flores notes.But Houston is not the only city where police officers learn about diversity.The Texas Commission on Law Enforcement requires that diversity and multiculturalism are part of the curriculum used for the basic training all police officers go through in the state.The courses are a reflection of the changing demographics in the United States because of the growth of minorities and they also teach why police officers must avoid racial profiling.There is also a class on basic Spanish due to the large Latino population of Texas.“My sense is that minimal requirements for understanding diverse peoples are probably being met adequately across the board,” comments Phillip Lyons, dean at the Criminal Justice College of Sam Houston State University.Lyons also thinks initiatives like HPD’s diversity course represent an added value for the training of its future officers.In addition to diversity, the concept of de-escalation has also become an increasingly important component of the training through the years.“I think the actions of the police have come under heightened scrutiny as it relates to how we deal with folks who have mental health problems or who are in crisis and, as a result of that, there is more attention given to training,” Lyons adds.Some of the tools police officers are instructed to use to de-escalate tense situations are prioritizing self-control and not behaving in an aggressive or condescending way, but paying attention to the nuances of non-verbal communication for certain communities can also be important.For example, officers are taught that some Latinos may prefer not to make eye contact not because they are lying, but because it is the way they show respect.Knowing how to work around personal space is relevant as well.Officer C.K. Traxler, who works for the Pasadena Police Department and teaches crisis intervention, explains that they teach cadets and police officers who go through training “to look for signs of stress in the person as you are approaching and if you see their stress level going up, you stop at that point or maybe even back up a little bit to reduce the stress that they’re already feeling.”Police officers frequently conduct traffic stops, which can present situations that turn confrontational and those are situations in which the training is useful.The protocol for police officers is that they must always say what is the reason for the stop and allow the driver to give an explanation for the traffic violation the officer deems he or she has committed, which can lower the stress of the situation. 00:00 /04:07 X To embed this piece of audio in your site, please use this code: Share
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only. (Phys.org)—Polycyclic aromatic hydrocarbons, such as graphene, have several potential uses as its π-conjugated structure lends itself to high stability and conductivity. Researchers are interested in exploring polycyclic aromatic hydrocarbons with boron and nitrogen atoms in an effort to explore the functionality and potential uses for polycyclic aromatic hydrocarbons. Journal information: Nature Chemistry Amino acids formed from the single-electron activation of carbon dioxide One polyatomic six-member ring that has not been isolated and studied is 1,3-dioxa-5-aza-2,4,6-triborinane, or DATB. DATB has a core B3NO2 ring that evidences some aromatic character. Hidetoshi Noda, Makoto Furutachi, Yasuko Asada, Masakatsu Shibasaki and Naoya Kumagai of the Institute of Microbial Chemistry in Tokyo (Bikaken) isolated and analyzed DATB using an m-terphenyl template. They demonstrated its ability to catalyze the direct coupling of several carboxylic acids with a variety of amines. Their DATB catalyst is thermally stable, structurally planar, and does not undergo hydrolysis. Their work appears in Nature Chemistry.The m-terphenyl template came out of the necessity to combine the B-N-B fragment to the O-B-O fragment to make the 1,2-dioxa-5-aza-2,4,6-triborinane ring. Using a stepwise synthesis, the first compound they made had the m-terphenyl template attached to the B-N-B portion of the DATB and a phenyl group attached to the boron of the O-B-O portion. The other compound that resulted from their initial syntheses had another m-terphenyl attached to the boron in the O-B-O portion of DATB instead of phenyl.The presence of DATB was confirmed with multinuclear NMR, mass spectrometry, and single-crystal x-ray diffraction. Notably, the DATB portion is planar and it exhibited offset face-to-face pi stacking. Additionally, it displayed slight aromaticity based on bond length and showed resistance toward hydrolytic cleavage.The next step was to determine if the DATB derivatives were able to catalyze amide bond formation. Boron has an affinity for amines, making this compound a possible option for catalyzing the direct coupling of amines and carboxylic acids. Noda et al. tested a variety of carboxylic acids because one of the major setbacks with amine and carboxylic acid coupling is that current methods are not generalizable for a variety of carboxylic acids, particularly bulky carboxylic acids. They tested a range of acids and amines whose coupling reactions were successfully catalyzed using DATB. They found that their DATB derivative successfully catalyzed the amide bond formation for sterically bulky aliphatic and aromatic carboxylic acids. They also found that indole-containing substrates did not require a protecting group. And, their method worked with benzoic acid and primary amines, α-branched amines, cyclic secondary amines. Using higher temperatures, they successfully coupled α-tertiary amines and acyclic secondary amines to benzoic acid. Additionally, they showed that the stereochemistry of α-chiral carboxylic acids and α-chiral amines were maintained.Their DATB derivative also worked well in the presence of various functional groups showing that the catalyst displayed good selectivity. Additionally, Noda et al. tested the catalyst’s ability to make peptide bonds with amino acids and biologically relevant amines by coupling Bz-Val-OH with H-Leu-NH2.This catalyst is remarkably versatile compared to other catalysts used for amine-carboxylic acid coupling. The authors contend that this is due to the distinct mechanism in which the three Lewis acid sites on the DATB core are used to bind the carboxylic acid and the amine countering the entropy cost in forming the bond. Chemical space for six-membered heterocycles composed of B, C, N and O atoms and the structure of DATBs. Credit: (c) Nature Chemistry (2017). DOI: 10.1038/nchem.2708 Citation: B3NO2 ring system serves as a versatile catalyst for amide bond formation (2017, February 22) retrieved 18 August 2019 from https://phys.org/news/2017-02-b3no2-versatile-catalyst-amide-bond.html More information: Hidetoshi Noda et al. Unique physicochemical and catalytic properties dictated by the B3NO2 ring system, Nature Chemistry (2017). DOI: 10.1038/nchem.2708AbstractThe expansion of molecular diversity beyond what nature can produce is a fundamental objective in chemical sciences. Despite the rich chemistry of boron-containing heterocycles, the 1,3-dioxa-5-aza-2,4,6-triborinane (DATB) ring system, which is characterized by a six-membered B3NO2 core, remains elusive. Here, we report the synthesis of m-terphenyl-templated DATB derivatives, displaying high stability and peculiar Lewis acidity arising from the three suitably arranged boron atoms. We identify a particular utility for DATB in the dehydrative amidation of carboxylic acids and amines, a reaction of high academic and industrial importance. The three boron sites are proposed to engage in substrate assembly, lowering the entropic cost of the transition state, in contrast with the operative mechanism of previously reported catalysts and amide coupling reagents. The distinct mechanistic pathway dictated by the DATB core will advance not only such amidations, but also other reactions driven by multisite activation. Explore further © 2017 Phys.org
Kolkata: The Special Task Force (STF) of Kolkata Police has busted an illegal firearms factory from Ghola area of North 24-Parganas and seized more than 90 firearms.The arms factory had been operating from a house in the area. Three persons, including the owner of the house, were held by the investigating agency for interrogation. The police had specific information that an illegal firearm manufacturing racket was operating from the house.A team of senior police officers raided the house on Wednesday morning and found the illegal factory in a ground floor room, which was used for stocking garments. Also Read – Rain batters Kolkata, cripples normal lifeThe owner of the house Kalachand Pal used to run a garment shop in the ground floor. A few months ago, he rented the floor to one Pappu Khan, who is suspected to be one of the main accused.The ground floor room had remained locked for some time. The police officers broke open the door and found some lathe machines inside the room. Various utensils related to the manufacturing of illegal firearms were also seized from the room.Khan has been absconding since the incident took place. Police are interrogating three persons, including the owner of the house. Raids are being conducted to nab the culprit. Also Read – Speeding Jaguar crashes into Mercedes car in Kolkata, 2 pedestrians killedPolice are trying to know if some other persons were involved in the incident.Police came to know the existence of the firearms factory after interrogating the accused, who were earlier arrested from Jagaddal in the same district in the last month.In the earlier incident, the STF had seized 60 semi-finished improvised firearms from an illegal arms factory in Jagaddal. Six persons were arrested with the semi-finished guns.Fake Indian currency notes (FICN) were also seized from Kolkata’s Maidan area during a raid last month.It may also be mentioned here that an illegal arms factory was busted from Ashokenagar area in North 24-Parganas by the district police and two persons were arrested for their alleged involvement in the racket in January this year.
The brain data revealed that the infant cries reduce attention to the task and triggered greater cognitive conflict processing than infant laughs. “Parental instinct appears to be hardwired yet no one talks about how this instinct might include cognition,” said David Haley from the University of Toronto.The team looked at infant vocalisations — in this case, audio clips of a baby laughing or crying —and its effect on adults who completed a cognitive conflict task. Also Read – ‘Playing Jojo was emotionally exhausting’They asked participants to rapidly identify the colour of a printed word while ignoring the meaning of the word itself. Brain activity was measured using electroencephalography (EEG), which took place immediately after a two-second audio clip of an infant vocalisation. Cognitive conflict processing is important because it controls attention — one of the most basic executive functions needed to complete a task or make a decision. A baby’s cry has been shown to cause aversion in adults but it could also be creating an adaptive response, “switching on” the cognitive control parents use in effectively responding to their child’s emotional needs while also addressing other demands in everyday life, Haley added in a paper published in the journal PLOS ONE. Also Read – Leslie doing new comedy special with Netflix“If an infant’s cry activates cognitive conflict in the brain, it could also be teaching parents how to focus their attention more selectively,” he added. The findings add to a growing body of research suggesting that infants occupy a privileged status in our neurobiological programming, one deeply rooted in our evolutionary past. But, as Haley noted, it also reveals an important adaptive cognitive function in the human brain.